Synthesis of a chiral building block for highly functionalized polycyclic ethers.
نویسندگان
چکیده
An efficient procedure for preparing enantiopure polycyclic ethers is reported. The protocol is based on the photo-oxidation/conjugate addition sequence over a chiral functionalized furan, which was prepared from commercially available tri-O-acetyl-D-glucal. The Michael addition step afforded two products with the same absolute configuration from a mixture of diastereomers.
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ورودعنوان ژورنال:
- Organic & biomolecular chemistry
دوره 12 39 شماره
صفحات -
تاریخ انتشار 2014